Here's a ranked listing of Fonts.com Web Fonts' top 100 most used Web fonts for June 2013:
Neue Helvetica
Proxima Nova
Trade Gothic
Futura
Gill Sans
Helvetica
Univers
DIN Next
Avenir
Avenir Next
Neue Frutiger
Frutiger
Linotype Univers
Frutiger Next
ITC Avant Garde Gothic
Trade Gothic Next
Humanist 777
Century Gothic
Futura T
Museo Sans
Univers Next
News Gothic
Adobe Caslon
Neue Helvetica
Neo Sans
Optima
Linotype Didot
Avenir Next
Baskerville Classico
Bembo
Arial
Agilita
Rockwell
Monotype News Gothic
DIN 1451
PMN Caecilia
ITC Franklin Gothic
VAG Rounded
Bodoni LT
Soho
Myriad
Brandon Grotesque
ITC Garamond
ITC Lubalin Graph
Corporate S
Helvetica Monospaced
ITC Conduit
News Gothic No.2
New Century Schoolbook
Twentieth Century
Soho Gothic
Neue Haas Grotesk
Sabon
Abadi
Gill Sans Infant
Adelle
Trade Gothic Next Soft Rounded
ITC Officina Sans
Times
Bembo Infant MT
ITC Century
Palatino
Neue Helvetica eText
Sackers Gothic
Klint
Frutiger Serif
Eurostile LT
Letter Gothic
Calibri
Neue Helvetica Arabic
Laurentian
Eurostile Next
Harmonia Sans
Bauer Bodoni
Camphor
Helvetica World
Garamond 3
Akko
Museo Slab
Memo
Adobe Garamond
ITC Franklin
ITC Fenice
Clarendon
Yakout
Effra
Minion
Novecento
MSung
New Caledonia
Monotype Baskerville
Plantin
Sassoon Sans
Museo
Ascender Serif
Compacta
Slate
Cachet
ITC Officina Serif
Aachen